Tetrahedron letters

An efficient synthesis of β-ketosilanes

GL Larson, IM de López-Cepero, LE Torres

文献索引：Larson, Gerald L.; Lopez-Cepero, Ingrid Montes de; Torres, Luz E. Tetrahedron Letters, 1984 , vol. 25, # 16 p. 1673 - 1676

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被引用次数: 22

摘要

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The reaction of α-silyl esters with an excess of a Grignard reagent leads to β-ketosilanes in good yield. ... Although some of the β-ketosilanes are more resistant to hydrolysis than others, we found these conditions to be best for general isolation of the desired product with a ...