The Journal of Organic Chemistry

Fingerprinting a transition-structure guest by a building-block approach with an incremental series of catalytic hosts. Structural requirements for glyme and. alpha.,. …

JC Hogan, RD Gandour

文献索引：Hogan, John C.; Gandour, Richard D. Journal of Organic Chemistry, 1992 , vol. 57, # 1 p. 55 - 61

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被引用次数: 25

摘要

(TI)(J. Org. Chem. 1991, 56, 2821-2826). Dissection of individual structural components and reassembly to the same structure of the complex verifies this model. The following kinetic studies of 4-nitrophenyl acetate in chlorobenzene have accomplished the task (a) methylbutylaminolysis catalyzed by GLM (n), n= 2-4;(b) methylbutylaminolysis catalyzed by a, w-dimethoxyalkanes, CH30-(CH2) n-OCH3, DME (n), n= 2-10 and 12; and (c) ...