Abstract The reactivity of the β-enamino ketones, 3-amino-1-(p-phenyl-substituted)-2-buten- 1-ones 1a-d and β-enamino esters. Ethyl-3-amino-3-(p-phenyl-substituted)-2-propenoates 5a-d were evaluated by systematic studies of the reactions with hydrazine and methylhydrazine by reactions with solid support K-10/ultrasound and homogeneous media (reflux in ethanol or dichloromethane) yielding pyrazole rings 2a-d, N-methylpyrazoles 3a- ...