Mechanism of the thermal decomposition of ethylsilane

RE Jardine, HE O'Neal, MA Ring…

文献索引：Jardine, R. E,; O'Neal, H. E.; Ring, M. A.; Beatie, M. E. Journal of Physical Chemistry, 1995 , vol. 99, p. 12507 - 12511

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被引用次数: 5

摘要

An earlier investigation in these laboratories of the thermally induced decomposition of EtSiH3 (ES)'by the comparativerate single-pulse shock-tube method (CR-SPST, T= 1165 & 80 K, Ptotal-3200 Torr, PES-6 Torr) showed that the ES decomposition is initiated by al, l-H2 elimination process yielding ethylsilylene (EtSiH) and that the ethylsilylene so produced decomposes to C2b and SiH2 with an activation energy of less than 30 kcal. Rate ...