Studies in the pyridine series. XXXIX. Ring cleavage in lithium aluminum hydride reductions of some dialkylpyridine methiodides

M Ferles, J Janoušková, O Fuchs

文献索引：Ferles,M. et al. Collection of Czechoslovak Chemical Communications, 1971 , vol. 36, p. 2389 - 2393

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被引用次数: 2

摘要

It has been shown in one of the earlier papers1 of this Series that the aluminum hydride (prepared in situ from lithium aluminum hydride and aluminum chloride) reductions of 2, 5- dimethylpyridine methiodide and 2-methyl-5-ethylpyridine methiodide are accompanied by cleavage of the pyridine ring under the formation of 2-methylaminomethyl-2, 4-hexadiene and 5-methylaminomethyl-2, 4-heptadiene, respectively. It was of interest if a similar ring ...