Direct observation of an intermediate in the oxygen atom rearrangement of 2-cyclopropylnitrobenzene in a strong acid

T Ohwada, M Kasuga, K Shudo

文献索引：Ohwada, Tomohiko; Kasuga, Mitsugu; Shudo, Koichi Journal of Organic Chemistry, 1990 , vol. 55, # 9 p. 2717 - 2719

全文：HTML全文

被引用次数: 5

摘要

The electron-donating effect of a cyclopropyl group on an aromatic ring is expected to stabilize a cation center more efficiently than that of a phenyl group.'P2 This generalization led us to anticipate that a cyclopropyl group might exert a similar stabilizing influence on the cationic center N02H+(a protonated nitro group)? and we therefore undertook the investigation of the behavior of 2-cyclopropylnitrobenzene in a strong acid. 2- ...