Organic compounds of fluorine. III. Reaction of trifluoromethyl alkyl ketones with acetylene

M Hudlický

文献索引：Hudlicky,M. Collection of Czechoslovak Chemical Communications, 1961 , vol. 26, p. 3140 - 3146

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摘要

The reaction of triftuoromethyl'alkyl ketones Ia-e with acetylene in the presence of calcium acetylide afforded triftuoromethylalkylethynylcarbinols Ila-e and the corresponding glycols IIlb-e. Under the conditions used trifluoroacetone (fa) underwent autocondensation to 1, 1, 1, 5, 5, 5-hexafiuoro-2-methyl-2-pentanol-4-one (IV) wllose carbamate has probably a cyclic structure Vb.