Ligand Displacement Reaction of Ru (η4-1, 5-COD)(η6-1, 3, 5-COT) with Lewis Bases

…, R Asakawa, C Nagata, T Miyasaka, N Komine…

文献索引：Hirano, Masafumi; Asakawa, Rie; Nagata, Chifumi; Miyasaka, Takashi; Komine, Nobuyuki; Komiya, Sanshiro Organometallics, 2003 , vol. 22, # 12 p. 2378 - 2386

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被引用次数: 10

摘要

Reaction of Ru (η4-1, 5-COD)(η6-1, 3, 5-COT)(1) with CNtBu causes initial substitution of 1, 3, 5-COT to produce Ru (η4-1, 5-COD)(CNtBu) 3, which slowly reacts with the liberated 1, 3, 5-COT to give Ru (η1: η3-COT)(CNtBu) 3, whereas reactions with alkyl phosphites, alkylphosphonites, and alkylphosphinites cause selective displacement of 1, 5-COD.