Electron delocalization as a controlling factor in the di-. pi.-methane rearrangement. Exploratory and mechanistic organic photochemistry. LXII

HE Zimmerman, AA Baum

文献索引：Zimmerman,H.E.; Baum,A.A. Journal of the American Chemical Society, 1971 , vol. 93, # 15 p. 3646 - 3653

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被引用次数: 33

摘要

Abstract: The photochemistry of 1, 1, 4-triphenyl-3, 3-dimethy1-1, 4-pentadiene was investigated. This triphenyldiene was found to rearrange on direct irradiation to give 1-a- styryl-2, 2-diphenyl-3, 3-dimethylcyclopropane as the major product. The alternative di-n- methane rearrangement product, 1-(2, 2-diphenylvinyl)-l-phenyl-2, 2-di-methylcyclopropane, was not produced. The rearrangement was shown to involve reaction of the singlet excited ...