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The Journal of Physical Chemistry

Hydrogen-bonded species of pyridinium haloacetates. 2. Thermometric behavior in aprotic solvents

B Chawla, SK Mehta

文献索引:Chawla, B.; Mehta, S. K. Journal of Physical Chemistry, 1984 , vol. 88, # 12 p. 2650 - 2655

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被引用次数: 16

摘要

The enthalpies of reaction of a series of substituted pyridines and of triethylamine, quinoline, and isoquinoline (for the sake of comparison) with trifluoroacetic acid (TFA) in chloroform were measured at 25 “C at final solution concentrations ranging from 1 X to 5 X lo-'M. The enthalpies of reaction of 2, 4, 6-trimethylpyridine, pyridine, and 4-cyanopyridine with trichloroacetic acid (TCA), dichloroacetic acid (DCA), monochloroacetic acid (MCA), and ...