Chemistry of sulfenic acids. 1. Synthesis of trimethylsilyl arenesulfenates (arenesulfenic acids)

…, R Ardecky, DJ Gosciniak, AJ Friedman…

文献索引：Davis, Franklin A.; Rizvi, Syed Q. A.; Ardecky, Robert; Gosciniak, Donald J.; Friedman, Arthur J.; Yocklovich, Steven G. Journal of Organic Chemistry, 1980 , vol. 45, # 9 p. 1650 - 1653

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被引用次数: 31

摘要

The importance of sulfenic acids (RSOH) as key intermediates in a wide variety of chemical transformations including biological ones is well recognized.'However, the difficulty in studying these species stems not only from their high reactivity but also from the lack of mild methods to generate them. Recently we reported that trimethylsilyl 2-nitrobenzenesulfenate (1) was a convenient, high-yield