Journal of the American Chemical Society

Ethyl β-Triethylsiloxycrotonate and Tetra-n-butylsilane

H Gilman, RN Clark

文献索引：Gilman; Clark Journal of the American Chemical Society, 1946 , vol. 68, p. 1675 Journal of the American Chemical Society, 1947 , vol. 69, p. 967

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被引用次数: 22

摘要

Hydrolysis of the siloxycrotonate by lo (r, hydrochloric acid gave acetone and hexaethyldisiloxane. Reaction of the siloxycrotonate with acetyl chloride yielded triethylsilyl chloride and ethyl P-acetoxycrotonate. It is possible that the procedure described by Hauser and co-workers' for C-alkylation with t-butyl alcohol by means of boron trifluoride might give some of the compound from triethylsilanol and acetoacetic ester. In a study of group and ...