Experimental and theoretical studies on bis (chlorocarbonyl) trisulfane, ClC (O) SSSC (O) Cl

…, MV Cozzarín, CO Della Védova, RM Romano

文献索引：Tobon, Yeny A.; Cozzarin, Melina V.; Della Vedova, Carlos O.; Romano, Rosana M. Journal of Molecular Structure, 2009 , vol. 930, # 1-3 p. 37 - 42

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被引用次数: 1

摘要

Bis (chlorocarbonyl) trisulfane, ClC (O) SSSC (O) Cl, was prepared by the reaction of (CH3) 2CHOC (S) SC (S) OCH (CH3) 2 and SO2Cl2 at 65° C. The compound was characterized and identified by vibrational spectroscopy, GC–MS, matrix isolation and photochemical studies as well as by quantum chemical calculations. Matrix photochemical studies and vibrational spectra were interpreted in terms of the presence of three forms with syn- ...