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vic-Iodothiocyanates and iodoisothiocyanates. Part 8. Addition of iodine–thiocyanogen to alkenes under ionic and radical conditions

…, PS Rutledge, GA Strange, PD Woodgate

文献索引:Cambie, Richard C.; Rutledge, Peter S.; Strange, Gary A.; Woodgate, Paul D. Heterocycles, 1982 , vol. 19, # 8 p. 1501 - 1510

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被引用次数: 9

摘要

Addition of iodine–thiocyanogen to alkenes in the dark proceeds by a regioselective ionic reaction to give mainly-iodoisothiocyanates, and under irradiation with uv light by a radical reaction to give mainly-iodothiocyanates. However, in the case of 1-methylene-4-t-