Methylbromosilanes

WF Gilliam, RN Meals, RO Sauer

文献索引：Gilliam; Meals; Sauer Journal of the American Chemical Society, 1946 , vol. 68, p. 1161

全文：HTML全文

被引用次数: 31

摘要

Mixtures of the methylbromosilanes were first prepared by Kochowla by the vapor phase reaction of methyl bromide with copper-silicon masses. This alkyl halide reacts smoothly at about 300'to give a dense liquid condensate from which we have isolated methyltribromosilane, dimethyldibromosilane, and trimethylbromxilane. In addition, indications of small amounts of tribromosilane and silicon tetrabromide have been found ...