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Tetrahedron

Synthesis of 1, 4, 5-trisubstituted-1, 2, 3-triazoles via coupling reaction of diaminomaleonitrile with aromatic diazonium salts

A Al-Azmi, AK Kalarikkal

文献索引:Al-Azmi, Amal; Kalarikkal, Anita K. Tetrahedron, 2013 , vol. 69, # 52 p. 11122 - 11129

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被引用次数: 7

摘要

Abstract A mild procedure for the preparation of 2-(5-amino-1-aryl-1H-1, 2, 3-triazol-4-yl)-2- iminoacetonitriles and 2-(5-amino-1-aryl-1H-1, 2, 3-triazol-4-yl)-2-oxoacetonitriles was achieved by the reaction of diaminomaleonitrile and phenyl/substituted phenyl diazonium chlorides. 4-Nitrophenyl diazonium chloride afforded 2-amino-3-(3-(4-nitrophenyl) triaz-1-en- 1-yl) maleonitrile. Triazole iminoacetonitrile and maleonitrile derivatives were reacted ...