Macromolecules

Polymeric nitrons. 2. Synthesis, irradiation and waveguide mode spectroscopy of polymeric nitrons derived from polymeric benzaldehydes and N- …

M Heinenberg, B Menges, S Mittler, H Ritter

文献索引：Heinenberg, Michael; Menges, Bernhard; Mittler, Silvia; Ritter, Helmut Macromolecules, 2002 , vol. 35, # 9 p. 3448 - 3455

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被引用次数: 19

摘要

Various vinylbenzaldehydes were prepared using the Heck reaction: 4-vinylbenzaldehyde (14), 3-vinylbenzaldehyde (15), 2-vinylbenzaldehyde (18a), 2-hydroxy-4-vinylbenzaldehyde (16) and 4-[(4-vinylbenzyl) oxy] benzaldehyde (6). The four monomers (6, 14, 15, 16) were polymerized using AIBN as initiator at 70° C for 24 h to yield the corresponding homopolymers (7, 19, 23, 25) and a copolymer (20) with styrene. The molecular weights ...