Reaction of amines with cyclopropylcarbinyl halides: SN2'or solvolysis?

MB Smith, RT Hrubiec, CA Zezza

文献索引：Smith, Michael B.; Hrubiec, Robert T.; Zezza, Charles A. Journal of Organic Chemistry, 1985 , vol. 50, # 24 p. 4815 - 4821

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被引用次数: 7

摘要

(complex m, 120 H), 3.02 (t, SCHz, 12 H). Anal. Calcd for C78H150S6: C, 73.2; H, 11.8; S, 15.0. Found: C, 72.9; H, 11.8; S, 15.2. Pentakis (et hylt hio)benzenet hiol(2). Colorless liquid; Pu- rified by preparative HPLC (silica gel: heptane eluent); 'H NMR (CDC13) (80 MHz) 6 1.15 (overlapping t, CH,, 15 H), 2.96 (overlapping q, CH2, 10 H), 6.77 (exchangeable s, SH, 1 H); IR ... C, 46.8; H, 6.4. Found C, 47.0; H, 6.4. 1,2,4,5-Tetrakis(ethylthio)benzene (3a). White ...