Electron-donating behaviour of aliphatic carboxylic acids in the photoreaction with 1, 2, 4, 5-tetracyanobenzene

K Tsujimoto, N Nakao, M Ohashi

文献索引：Tsujimoto, Kazuo; Nakao, Nobuhisa; Ohashi, Mamoru Journal of the Chemical Society, Chemical Communications, 1992 , # 4 p. 366 - 367

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被引用次数: 17

摘要

Photochemical alkylation with aliphatic carboxylic acids is an intriguing method not only in synthetic chemistry but also in mechanistic photochemistry. As a most promising candidate for the alkylation, an electron donor-acceptor (EDA) system is proposed in the photochemical reaction. The EDA-type photodecarboxylation of carboxylic acids has been explored by Davidsonl and Libman.2 The carboxylic acids used were limited to the acids having a 0-heteroatom ...