Journal of the American Chemical Society

Biosynthesis of sulfur compounds. Elucidation of the stereochemistry of the conversion of 3-(methylthio) propylglucosinolate into allylglucosinolate (sinigrin)

RJ Parry, MV Naidu

文献索引：Parry; Naidu Journal of the American Chemical Society, 1982 , vol. 104, # 11 p. 3217 - 3219

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被引用次数: 7

摘要

Finally, 14 was reduced to the corresponding aldehyde with Red-a1 and morpholine]" and DL-[~(RS)-~ H] homomethionine (15) obtained by Bucherer synthesis (21%). DL-[~(R)-and 4 (S)-3H]-homomethionine (16, 17) were prepared by a variation of the same reaction sequence. If~ rmyl-~ H] Benzyloxybenzaldehyde (7) was reduced with the adduct of 9- borabicyclononane (9-BBN) and (-)-or (+)-a-pinene" to give [1 (R)-and 1 (S)-3H] ...