Tetrahedron letters

Chemistry of singlet oxygen: Isolation and characterization of a stable allene oxide from a fulvene endoperoxide

I Erden, J Drummond, R Alstad, F Xu

文献索引：Erden, Ihsan; Drummond, Jane; Alstad, Roger; Xu, Fupei Tetrahedron Letters, 1993 , vol. 34, # 8 p. 1255 - 1258

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被引用次数: 18

摘要

Abstract Decomposition of the saturated endoperoxide derived from 6-t-butylfulvene at 1OOC gives a stable allene oxide which was isolated and characterized by spectroscopy and chemical transformations. The thermal isomerization of the parent unsaturated system is also described and the decomposition mechanisms are discussed.