Photochemical reaction between 1, 4-naphthalenedicarbonitrile and. alpha.-substituted benzylic derivatives

A Sulpizio, A Albini, N d'Alessandro…

文献索引：Sulpizio, Ada; Albini, Angelo; d'Alessandro, Nicola; Fasani, Elisa; Pietra, Silvio Journal of the American Chemical Society, 1989 , vol. 111, # 15 p. 5773 - 5777

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被引用次数: 42

摘要

Abstract: The photochemical reaction of 1, 4-naphthaIenedicarbonitrile (NDN) with benzylic derivatives of the general formula PhCHRX (R= H, Ph; X= H, C, 0, S, Si, Sn-bonded substituents) has been investigated. The competition between CH and CX bond cleavage in the photochemically created radical cation PhCHRX" is revealed by the different chemical products formed, viz. 5, 1l-methanodibenzo [a, e] cyclooctenes (2), from proton transfer ...