Bulletin of the Chemical Society of Japan

Regio-and stereoselective cross-aldol reactions via dialkylboryl triflates.

T Inoue, T Mukaiyama

文献索引：Inoue, Tan; Mukaiyama, Teruaki Bulletin of the Chemical Society of Japan, 1980 , vol. 53, # 1 p. 174 - 178

被引用次数: 151

摘要

New borylating reagents,(Bu 2 BOTf and 9-BBNOTf), were prepared in high yields. The triflates reacted with enolizable ketones in the presence of tertiary amines to generate selectively one of the regioisomers of vinyloxyboranes by the choice of the reagents (the dialkylboryl triflates and tertiary amines) under mild reaction conditions. Vinyloxyboranes thus generated showed remarkable reactivity toward aldehydes to give only one ...