Spin States and Stability of FeIII Complexes of Ligands with Carboxamido Nitrogen and Phenolato Oxygen Donors

…, MM Olmstead, PK Mascharak

文献索引：Marlin, Dana S.; Olmstead, Marilyn M.; Mascharak, Pradip K. European Journal of Inorganic Chemistry, 2002 , # 4 p. 859 - 865

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被引用次数: 16

摘要

Abstract As part of our attempts to prepare Fe III complexes with “tunable” spin states, we have synthesized three novel six-coordinate Fe III complexes containing both carboxamido nitrogen (N amido) and phenolato oxygen (O phen) donors in their ligand framework. Since it has already been shown that carboxamido nitrogen donors usually stabilize Fe III in a low spin configuration, while phenolato oxygens tend to stabilize Fe III in a high spin state, we ...