The Journal of Organic Chemistry

The synthesis and spectra of. alpha.,. beta.-unsaturated aliphatic azoxy compounds

BT Gillis, JD Hagarty

文献索引：Gillis,B.T.; Hagarty,J.D. Journal of Organic Chemistry, 1967 , vol. 32, p. 95 - 96

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被引用次数: 18

摘要

Per acid oxidation of cy,@-unsaturated aliphatic azo compounds has resulted in the formation of the corresponding a,@-unsaturated aliphatic azoxy compounds. The position of the oxygen atom in the azoxy group has been found to depend on alkyl substitution. Thus, 2- (methy1azo) propene (IV) and 1-(methy1azo) cyclohexene (VI) gave 2-(methyl-NNO-azoxy) propene (V) and 1-(methyl-NNO-azoxy) cyclohexene (VII), respectively. Oxidation of 2-( ...