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举例 :可输入Filippa Pettersson 或者 Cancer Res. 75(6) , 1102-12, (2015) 或者10.1002/anie.201600521

The Journal of Organic Chemistry

A method for mild photochemical oxidation; conversion of phenacyl sulfides into carbonyl compounds

E Vedejs, DA Perry

文献索引：Vedejs, E.; Perry, D. A. Journal of Organic Chemistry, 1984 , vol. 49, # 3 p. 573 - 575

全文：HTML全文

被引用次数: 27

摘要

Summary: Sunlamp irradiation of phenacyl sulfides PhCOCH2SCHRR'affords thiocarbonyl compounds S= CRR'that can be trapped in high yield by using the nitronate CH, CH= N+(OTBS) O-; the heterocycle 3 resulting from 1, 3-dipolar cycloaddition is cleaved rapidly by fluoride ion to give ketones or aldehydes.

cyclododecanethiol结构式

cyclododecanethiol

2-氯苯乙酮结构式

~%

2-cyclododecylsulfanyl-1-phenylethanone结构式

2-cyclododecyls...

未登录结构式

2-氯苯乙酮结构式

~%

(2-phenacylsulfanylcyclohexyl) acetate结构式

(2-phenacylsulf...

2-(acetylthio)-1-phenylethyl acetate结构式

2-(acetylthio)-...

2-氯苯乙酮结构式

~%

(2-phenacylsulfanyl-1-phenylethyl) acetate结构式

(2-phenacylsulf...

2-乙酰基硫代苯乙酮结构式

2-乙酰基硫代苯乙酮

~%

3-phenacylsulfanylcyclohexan-1-one结构式

3-phenacylsulfa...

2-氯苯乙酮结构式

~%

3-phenacylsulfanylcyclohexan-1-one结构式

3-phenacylsulfa...

环己烯酮结构式

2-巯基-1-苯乙酮结构式

2-巯基-1-苯乙酮

~%

3-phenacylsulfanylcyclohexan-1-one结构式

3-phenacylsulfa...

2-乙酰基硫代苯乙酮结构式

2-乙酰基硫代苯乙酮

~%

2-methyl-5-phenacylsulfanylnonan-3-one结构式

2-methyl-5-phen...

2-氯苯乙酮结构式

~%

2-methyl-5-phenacylsulfanylnonan-3-one结构式

2-methyl-5-phen...

未登录结构式

2-巯基-1-苯乙酮结构式

2-巯基-1-苯乙酮

~%

2-methyl-5-phenacylsulfanylnonan-3-one结构式

2-methyl-5-phen...

未登录结构式

~%

2-acetyl-3-phenylmethoxybutanal结构式

2-acetyl-3-phen...

(1-phenacylsulfanyl-3-phenylmethoxybutan-2-yl) acetate结构式

(1-phenacylsulf...

~%

2-acetyl-3-phenylmethoxybutanal结构式

2-acetyl-3-phen...

1-(5-butyl-2-((tert-butyldimethylsilyl)oxy)-3-methyl-1,4,2-oxathiazolidin-5-yl)-3-methylbutan-2-one结构式

1-(5-butyl-2-((...

~58%

2-methylnonane-3,5-dione结构式

2-methylnonane-...

未登录结构式

~%

2-methylnonane-3,5-dione结构式

2-methylnonane-...

2-methyl-5-phenacylsulfanylnonan-3-one结构式

2-methyl-5-phen...

~%

2-methylnonane-3,5-dione结构式

2-methylnonane-...

环己烯酮结构式

~%

3-methylsulfanylcyclohex-2-en-1-one结构式

3-methylsulfany...

3-phenacylsulfanylcyclohexan-1-one结构式

3-phenacylsulfa...

~%

3-methylsulfanylcyclohex-2-en-1-one结构式

3-methylsulfany...

3-sulfanylcyclohex-2-en-1-one结构式

3-sulfanylcyclo...

碘甲烷结构式

~%

3-methylsulfanylcyclohex-2-en-1-one结构式

3-methylsulfany...

2-((tert-butyldimethylsilyl)oxy)-3-methyl-1-oxa-4-thia-2-azaspiro[4.5]decan-6-yl acetate结构式

2-((tert-butyld...

~%

2-OXOCYCLOHEXYL ACETATE结构式

2-OXOCYCLOHEXYL...

未登录结构式

~%

2-OXOCYCLOHEXYL ACETATE结构式

2-OXOCYCLOHEXYL...

(2-phenacylsulfanylcyclohexyl) acetate结构式

(2-phenacylsulf...

~%

2-OXOCYCLOHEXYL ACETATE结构式

2-OXOCYCLOHEXYL...

2-((tert-butyldimethylsilyl)oxy)-3-methyl-1-oxa-4-thia-2-azaspiro[4.5]decan-7-one结构式

2-((tert-butyld...

~%

1,3-环己二酮结构式

1,3-环己二酮

3-phenacylsulfanylcyclohexan-1-one结构式

3-phenacylsulfa...

~%

1,3-环己二酮结构式

1,3-环己二酮

3-苯基-1-丙烷硫醇结构式

3-苯基-1-丙烷硫醇

~%

3-methyl-5-(2-phenylethyl)-1,4,2-oxathiazole结构式

3-methyl-5-(2-p...

1-phenyl-2-(3-phenylpropylsulfanyl)ethanone结构式

1-phenyl-2-(3-p...

~%

3-methyl-5-(2-phenylethyl)-1,4,2-oxathiazole结构式

3-methyl-5-(2-p...

2-((tert-butyldimethylsilyl)oxy)-3-methyl-5-phenethyl-1,4,2-oxathiazolidine结构式

2-((tert-butyld...

~%

3-苯丙醛结构式

3-methyl-5-(2-phenylethyl)-1,4,2-oxathiazole结构式

3-methyl-5-(2-p...

3-phenacylsulfanylcyclohexan-1-one结构式

3-phenacylsulfa...

~%

3-sulfanylcyclohex-2-en-1-one结构式

3-sulfanylcyclo...

环己烯酮结构式

~%

3-sulfanylcyclohex-2-en-1-one结构式

3-sulfanylcyclo...