Tetrahedron Letters

A new method for the synthesis of dichlorophosphines

AN Tavtorkin, SA Toloraya, EE Nifant'ev, IE Nifant'ev

文献索引：Tavtorkin, Alexander N.; Toloraya, Sofia A.; Nifant'Ev, Eduard E.; Nifant'Ev, Ilya E. Tetrahedron Letters, 2011 , vol. 52, # 7 p. 824 - 825

全文：HTML全文

被引用次数: 4

摘要

Alkyl- and aryl-dichlorophosphines represent valuable precursors for the preparation of various sophisticated derivatives of P(III), including compounds with P–C, P–O and P–N bonds, which are widely applied in homogeneous catalysis as ligands. 1 There are two key synthetic routes leading to these compounds (Scheme 1). ... Key routes to dichlorophosphines. Key routes to dichlorophosphines. ... The former method is the most simple and widely used, however, ...