Helvetica chimica acta

Oxidative Breaking of Long??Chain Acetylenic Enol Ethers of Glycerol of the Marine Sponges Raspailia pumila and of Model Compounds with Aerial Oxygen

G Guella, I Mancini, F Pietra

文献索引：Guella, Graziano; Mancini, Ines; Pietra, Francesco Helvetica Chimica Acta, 1987 , vol. 70, p. 1400 - 1411

全文：HTML全文

被引用次数: 15

摘要

Abstract The raspailynes (novel long-chain enol ethers of glycerol having the enol ethers double bond conjugated in sequence, to an acetylenic and an olefinic bond, isolated from the North-East-Atlantic sponges Raspailia pumila and R. ramosa) are stable under normal hydrolytic conditions for enol ethers. In contrast, when their solutions are evaporated, these lipids such as raspailyne Bl (=(−))-3-[(1Z, 5Z)-(tetradeca-1, 5-dien-3-ynyl) oxy]-1, 2- ...