Thermolysis of vinyl chloride in nitrogen; rates and products between 601??681° C

JA Manion, R Louw

文献索引：Manion, Jeffrey A.; Louw, Robert Recueil des Travaux Chimiques des Pays-Bas, 1986 , vol. 105, p. 442 - 448

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被引用次数: 5

摘要

Abstract In a 10-15-fold excess of nitrogen, at normal pressure and with τ ca. 3 s, decomposition of vinyl chloride (VC) sets in at about 550 C. At 680 C about 35% decomposition takes place. Major products in this region are HCl, acetylene, 2- chlorobutadiene and vinylacetylene (1-buten-3-yne). At higher temperatures formation of tar and soot becomes increasingly important. A reaction mechanism in accord with the ...