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举例 :可输入Filippa Pettersson 或者 Cancer Res. 75(6) , 1102-12, (2015) 或者10.1002/anie.201600521

Synthesis and reactions of phosphoryl-substituted sulfines

…, BHM Lammerink, B Zwanenburg

文献索引：Porskamp, Pascal A. T. W.; Lammerink, Ben H. M.; Zwanenburg, Binne Journal of Organic Chemistry, 1984 , vol. 49, # 2 p. 263 - 268

全文：HTML全文

被引用次数: 25

摘要

The synthesis of a variety of phosphoryl-substituted sulfines 5 by the reaction of a-silyl carbanions with sulfur dioxide is described. For characterization purposes the prepared sulfines were converted into their cycloadducts 6 with 2, 3-dimethyl-l, 3-butadiene.( Diethoxyphosphory1) phenylsulfine 5a was reacted with alkyllithium to give a-phosphoryl carbanions, which on treatment with aromatic aldehydes gave a,@-unsaturated sulfoxides ...

DIETHYL(TRIMETHYLSILYLMETHYL)PHOSPHONATE结构式

DIETHYL(TRIMETH...

~%

ethyl 3-diethoxyphosphoryl-3-trimethylsilylpropanoate结构式

ethyl 3-diethox...

diphenyl((trimethylsilyl)methyl)phosphine oxide结构式

diphenyl((trime...

~%

(1-diphenylphosphoryl-2-phenylethyl)-trimethylsilane结构式

(1-diphenylphos...

DIETHYL(TRIMETHYLSILYLMETHYL)PHOSPHONATE结构式

DIETHYL(TRIMETH...

~%

1-diethoxyphosphoryl-3-methylsulfanyl-1-sulfinylpropane结构式

1-diethoxyphosp...

(1-diethoxyphosphoryl-3-methylsulfanylpropyl)-trimethylsilane结构式

(1-diethoxyphos...

~%

1-diethoxyphosphoryl-3-methylsulfanyl-1-sulfinylpropane结构式

1-diethoxyphosp...

diphenyl((trimethylsilyl)methyl)phosphine oxide结构式

diphenyl((trime...

~%

[phenyl(1-sulfinylethyl)phosphoryl]benzene结构式

[phenyl(1-sulfi...

(1-trimethylsilylethyl)diphenylphosphine oxide结构式

(1-trimethylsil...

~%

[phenyl(1-sulfinylethyl)phosphoryl]benzene结构式

[phenyl(1-sulfi...

三甲基氯硅烷结构式

三甲基氯硅烷

(3-甲基苄基)膦酸二乙酯结构式

(3-甲基苄基)膦酸二乙酯

~%

[diethoxyphosphoryl-(3-methylphenyl)methyl]-trimethylsilane结构式

[diethoxyphosph...

Diethyl (2-naphtylmethyl)phosphonate结构式

Diethyl (2-naph...

~%

2-(diethoxyphosphorylmethylsulfinyl)naphthalene结构式

2-(diethoxyphos...

diethyl (naphthalen-2-yl(trimethylsilyl)methyl)phosphonate结构式

diethyl (naphth...

~%

2-(diethoxyphosphorylmethylsulfinyl)naphthalene结构式

2-(diethoxyphos...

2-(diethoxyphosphorylmethyl)-1,4-dimethylbenzene结构式

2-(diethoxyphos...

~%

2-(diethoxyphosphorylmethylsulfinyl)-1,4-dimethylbenzene结构式

2-(diethoxyphos...

diethyl ((2,5-dimethylphenyl)(trimethylsilyl)methyl)phosphonate结构式

diethyl ((2,5-d...

~%

2-(diethoxyphosphorylmethylsulfinyl)-1,4-dimethylbenzene结构式

2-(diethoxyphos...

(3-甲基苄基)膦酸二乙酯结构式

(3-甲基苄基)膦酸二乙酯

~%

1-(diethoxyphosphorylmethylsulfinyl)-3-methylbenzene结构式

1-(diethoxyphos...

[diethoxyphosphoryl-(3-methylphenyl)methyl]-trimethylsilane结构式

[diethoxyphosph...

~%

1-(diethoxyphosphorylmethylsulfinyl)-3-methylbenzene结构式

1-(diethoxyphos...

三甲基氯硅烷结构式

三甲基氯硅烷

二乙基(苯基硫代甲基)磷酸酯结构式

二乙基(苯基硫代甲基)磷酸酯

~%

[diethoxyphosphoryl(phenylsulfanyl)methyl]-trimethylsilane结构式

[diethoxyphosph...

三甲基氯硅烷结构式

三甲基氯硅烷

(甲硫甲基)磷酸二乙酯结构式

(甲硫甲基)磷酸二乙酯

~%

[diethoxyphosphoryl(methylsulfanyl)methyl]-trimethylsilane结构式

[diethoxyphosph...

二乙基(苯基硫代甲基)磷酸酯结构式

二乙基(苯基硫代甲基)磷酸酯

~%

diethoxyphosphorylmethylsulfinylsulfanylbenzene结构式

diethoxyphospho...

[diethoxyphosphoryl(phenylsulfanyl)methyl]-trimethylsilane结构式

[diethoxyphosph...

~%

diethoxyphosphorylmethylsulfinylsulfanylbenzene结构式

diethoxyphospho...

diphenyl((trimethylsilyl)methyl)phosphine oxide结构式

diphenyl((trime...

~%

(2-diphenylphosphoryl-2-sulfinylethyl)benzene结构式

(2-diphenylphos...

(1-diphenylphosphoryl-2-phenylethyl)-trimethylsilane结构式

(1-diphenylphos...

~%

(2-diphenylphosphoryl-2-sulfinylethyl)benzene结构式

(2-diphenylphos...

三甲基氯硅烷结构式

三甲基氯硅烷

氯甲基膦酸二乙酯结构式

氯甲基膦酸二乙酯

~%

[chloro(diethoxyphosphoryl)methyl]-trimethylsilane结构式

[chloro(diethox...

三甲基氯硅烷结构式

三甲基氯硅烷

未登录结构式

~%

[diphenylphosphoryl(methylsulfanyl)methyl]-trimethylsilane结构式

[diphenylphosph...

三甲基氯硅烷结构式

三甲基氯硅烷

苄基二苯基氧化膦结构式

苄基二苯基氧化膦

~%

[diphenylphosphoryl(phenyl)methyl]-trimethylsilane结构式

[diphenylphosph...

O,O-diethyl α-trimethylsilylbenzylphosphonate结构式

O,O-diethyl α-t...

~%

[diethoxyphosphoryl(methylsulfinyl)methyl]benzene结构式

[diethoxyphosph...

苄基膦酸二乙酯结构式

苄基膦酸二乙酯

~%

[diethoxyphosphoryl(methylsulfinyl)methyl]benzene结构式

[diethoxyphosph...

甲基锂结构式

(Diethoxyphosphoryl)phenylsulfine结构式

(Diethoxyphosph...

~%

[diethoxyphosphoryl(methylsulfinyl)methyl]benzene结构式

[diethoxyphosph...

O,O-diethyl α-trimethylsilylbenzylphosphonate结构式

O,O-diethyl α-t...

~%

[butylsulfinyl(diethoxyphosphoryl)methyl]benzene结构式

[butylsulfinyl(...

苄基膦酸二乙酯结构式

苄基膦酸二乙酯

~%

[butylsulfinyl(diethoxyphosphoryl)methyl]benzene结构式

[butylsulfinyl(...

正丁基锂结构式

(Diethoxyphosphoryl)phenylsulfine结构式

(Diethoxyphosph...

~%

[butylsulfinyl(diethoxyphosphoryl)methyl]benzene结构式

[butylsulfinyl(...

O,O-diethyl α-trimethylsilylbenzylphosphonate结构式

O,O-diethyl α-t...

~%

[butan-2-ylsulfinyl(diethoxyphosphoryl)methyl]benzene结构式

[butan-2-ylsulf...

苄基膦酸二乙酯结构式

苄基膦酸二乙酯

~%

[butan-2-ylsulfinyl(diethoxyphosphoryl)methyl]benzene结构式

[butan-2-ylsulf...

仲丁基锂结构式

(Diethoxyphosphoryl)phenylsulfine结构式

(Diethoxyphosph...

~%

[butan-2-ylsulfinyl(diethoxyphosphoryl)methyl]benzene结构式

[butan-2-ylsulf...

三甲基氯硅烷结构式

三甲基氯硅烷

二苯基((苯硫基)甲基)氧化膦结构式

二苯基((苯硫基)甲基)氧化膦

~%

[diphenylphosphoryl(phenylsulfanyl)methyl]-trimethylsilane结构式

[diphenylphosph...

(甲硫甲基)磷酸二乙酯结构式

(甲硫甲基)磷酸二乙酯

~%

1-[ethoxy(methylsulfanylsulfinylmethyl)phosphoryl]oxyethane结构式

1-[ethoxy(methy...

[diethoxyphosphoryl(methylsulfanyl)methyl]-trimethylsilane结构式

[diethoxyphosph...

~%

1-[ethoxy(methylsulfanylsulfinylmethyl)phosphoryl]oxyethane结构式

1-[ethoxy(methy...

未登录结构式

~%

[methylsulfanylsulfinylmethyl(phenyl)phosphoryl]benzene结构式

[methylsulfanyl...

[diphenylphosphoryl(methylsulfanyl)methyl]-trimethylsilane结构式

[diphenylphosph...

~%

[methylsulfanylsulfinylmethyl(phenyl)phosphoryl]benzene结构式

[methylsulfanyl...

苄基二苯基氧化膦结构式

苄基二苯基氧化膦

~%

[diphenylphosphoryl(methylsulfinyl)methyl]benzene结构式

[diphenylphosph...

[diphenylphosphoryl(phenyl)methyl]-trimethylsilane结构式

[diphenylphosph...

~%

[diphenylphosphoryl(methylsulfinyl)methyl]benzene结构式

[diphenylphosph...

甲基锂结构式

[benzenesulfinylmethyl(phenyl)phosphoryl]benzene结构式

[benzenesulfiny...

~%

[diphenylphosphoryl(methylsulfinyl)methyl]benzene结构式

[diphenylphosph...

DIETHYL(TRIMETHYLSILYLMETHYL)PHOSPHONATE结构式

DIETHYL(TRIMETH...

~%

(1-diethoxyphosphoryl-2-phenylethyl)-trimethylsilane结构式

(1-diethoxyphos...

苄基二苯基氧化膦结构式

苄基二苯基氧化膦

~%

[benzenesulfinylmethyl(phenyl)phosphoryl]benzene结构式

[benzenesulfiny...

[diphenylphosphoryl(phenyl)methyl]-trimethylsilane结构式

[diphenylphosph...

~%

[benzenesulfinylmethyl(phenyl)phosphoryl]benzene结构式

[benzenesulfiny...

二苯基((苯硫基)甲基)氧化膦结构式

二苯基((苯硫基)甲基)氧化膦

~%

[phenyl(phenylsulfanylsulfinylmethyl)phosphoryl]benzene结构式

[phenyl(phenyls...

[diphenylphosphoryl(phenylsulfanyl)methyl]-trimethylsilane结构式

[diphenylphosph...

~%

[phenyl(phenylsulfanylsulfinylmethyl)phosphoryl]benzene结构式

[phenyl(phenyls...

(Diethoxyphosphoryl)phenylsulfine结构式

(Diethoxyphosph...

碘甲烷结构式

~%

(1-diethoxyphosphoryl-1-methylsulfinylethyl)benzene结构式

(1-diethoxyphos...

O,O-diethyl α-trimethylsilylbenzylphosphonate结构式

O,O-diethyl α-t...

~%

(2-butylsulfinyl-2-diethoxyphosphoryl-2-phenylethyl)benzene结构式

(2-butylsulfiny...

苄基膦酸二乙酯结构式

苄基膦酸二乙酯

~%

(2-butylsulfinyl-2-diethoxyphosphoryl-2-phenylethyl)benzene结构式

(2-butylsulfiny...

溴化苄结构式

(Diethoxyphosphoryl)phenylsulfine结构式

(Diethoxyphosph...

~%

(2-butylsulfinyl-2-diethoxyphosphoryl-2-phenylethyl)benzene结构式

(2-butylsulfiny...

O,O-diethyl α-trimethylsilylbenzylphosphonate结构式

O,O-diethyl α-t...

~%

(2-diethoxyphosphoryl-2-phenylethenyl)benzene结构式

(2-diethoxyphos...

苄基膦酸二乙酯结构式

苄基膦酸二乙酯

~%

(2-diethoxyphosphoryl-2-phenylethenyl)benzene结构式

(2-diethoxyphos...

溴化苄结构式

~%

(2-diethoxyphosphoryl-2-phenylethenyl)benzene结构式

(2-diethoxyphos...

(Diethoxyphosphoryl)phenylsulfine结构式

(Diethoxyphosph...

~%

(2-diethoxyphosphoryl-2-phenylethenyl)benzene结构式

(2-diethoxyphos...

(2-butylsulfinyl-2-diethoxyphosphoryl-2-phenylethyl)benzene结构式

(2-butylsulfiny...

~%

(2-diethoxyphosphoryl-2-phenylethenyl)benzene结构式

(2-diethoxyphos...

DIETHYL(TRIMETHYLSILYLMETHYL)PHOSPHONATE结构式

DIETHYL(TRIMETH...

~%

(1-diethoxyphosphoryl-3-methylsulfanylpropyl)-trimethylsilane结构式

(1-diethoxyphos...

氯甲基膦酸二乙酯结构式

氯甲基膦酸二乙酯

~%

diethoxyphosphorylmethanesulfinyl chloride结构式

diethoxyphospho...

[chloro(diethoxyphosphoryl)methyl]-trimethylsilane结构式

[chloro(diethox...

~%

diethoxyphosphorylmethanesulfinyl chloride结构式

diethoxyphospho...

DIETHYL(TRIMETHYLSILYLMETHYL)PHOSPHONATE结构式

DIETHYL(TRIMETH...

~%

1-diethoxyphosphoryl-1-sulfinylethane结构式

1-diethoxyphosp...

Diethyl(1-(trimethylsilyl)ethyl)phosphonate结构式

Diethyl(1-(trim...

~%

1-diethoxyphosphoryl-1-sulfinylethane结构式

1-diethoxyphosp...

DIETHYL(TRIMETHYLSILYLMETHYL)PHOSPHONATE结构式

DIETHYL(TRIMETH...

~%

(2-diethoxyphosphoryl-2-ethylsulfinylethenyl)benzene结构式

(2-diethoxyphos...

(1-diethoxyphosphoryl-2-phenylethyl)-trimethylsilane结构式

(1-diethoxyphos...

~%

(2-diethoxyphosphoryl-2-ethylsulfinylethenyl)benzene结构式

(2-diethoxyphos...

(2-diethoxyphosphoryl-2-sulfinylethyl)benzene结构式

(2-diethoxyphos...

碘乙烷结构式

~%

1-(Ethylthio)-1-(diethoxyphosphoryl)-2-phenylethene结构式

1-(Ethylthio)-1...

(2-diethoxyphosphoryl-2-ethylsulfinylethenyl)benzene结构式

(2-diethoxyphos...

diphenyl((trimethylsilyl)methyl)phosphine oxide结构式

diphenyl((trime...

~%

(2-diphenylphosphoryl-2-methylsulfinylethenyl)benzene结构式

(2-diphenylphos...

(1-diphenylphosphoryl-2-phenylethyl)-trimethylsilane结构式

(1-diphenylphos...

~%

(2-diphenylphosphoryl-2-methylsulfinylethenyl)benzene结构式

(2-diphenylphos...

(2-diphenylphosphoryl-2-sulfinylethyl)benzene结构式

(2-diphenylphos...

碘甲烷结构式

~%

(2-diphenylphosphoryl-2-methylsulfinylethenyl)benzene结构式

(2-diphenylphos...

三甲基氯硅烷结构式

三甲基氯硅烷

DIETHYL(TRIMETHYLSILYLMETHYL)PHOSPHONATE结构式

DIETHYL(TRIMETH...

~%

[diethoxyphosphoryl(trimethylsilyl)methyl]-trimethylsilane结构式

[diethoxyphosph...

DIETHYL(TRIMETHYLSILYLMETHYL)PHOSPHONATE结构式

DIETHYL(TRIMETH...

~%

(1-diethoxyphosphoryl-2-trimethylsilylethyl)-trimethylsilane结构式

(1-diethoxyphos...

DIETHYL(TRIMETHYLSILYLMETHYL)PHOSPHONATE结构式

DIETHYL(TRIMETH...

~%

(2-diethoxyphosphoryl-2-sulfinylethyl)benzene结构式

(2-diethoxyphos...

(1-diethoxyphosphoryl-2-phenylethyl)-trimethylsilane结构式

(1-diethoxyphos...

~%

(2-diethoxyphosphoryl-2-sulfinylethyl)benzene结构式

(2-diethoxyphos...

DIETHYL(TRIMETHYLSILYLMETHYL)PHOSPHONATE结构式

DIETHYL(TRIMETH...

~%

2-(2-diethoxyphosphoryl-2-sulfinylethyl)-1,3,5-trimethylbenzene结构式

2-(2-diethoxyph...

diethyl (2-mesityl-1-(trimethylsilyl)ethyl)phosphonate结构式

diethyl (2-mesi...

~%

2-(2-diethoxyphosphoryl-2-sulfinylethyl)-1,3,5-trimethylbenzene结构式

2-(2-diethoxyph...