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Conversion of pentahalogenated phenols by microperoxidase-8/H2O2 to benzoquinone-type products

…, C Veeger, PJ van Bladeren, C Laane…

文献索引:Osman, Ahmed M.; Posthumus, Maarten A.; Veeger, Cees; Van Bladeren, Peter J.; Laane, Colja; Rietjens, Ivonne M.C.M. Chemical Research in Toxicology, 1998 , vol. 11, # 11 p. 1319 - 1325

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被引用次数: 13

摘要

This study reports the microperoxidase-8 (MP8)/H2O2-catalyzed dehalogenation of pentafluorophenol and pentachlorophenol, compounds whose toxic effects and persistence in the environment are well documented. The primary products of this dehalogenation reaction appear to be the corresponding tetrahalo-p-benzoquinones. Under the conditions used, the fluorinated phenol and its intermediate products are more susceptible to ...