Tetrahedron Letters

Solid-phase synthesis on functionalised fluoropolymer resins. Part 2: Preparation and properties of functional Merrifield-type resins possessing a perfluorinated …

S Liu, M Akhtar, D Gani

文献索引：Liu, Shuyuan; Akhtar, Mahmoud; Gani, David Tetrahedron Letters, 2000 , vol. 41, # 22 p. 4493 - 4497

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被引用次数: 6

摘要

Monomers α, β, β-trifluorostyrene and 4-methyl-α, β, β-trifluorostyrene were prepared and were copolymerised under free-radical emulsion conditions to give highly stable, well defined lipophilic polymer resins. Benzylic halogenation of the polymer products gave 4- chloromethyl and 4-bromomethyl derivatives which could be elaborated through nucleophilic displacement of halide. The reaction of 4-fluorophenol with the 4- ...