Highly regioselective reaction of zirconocene-alkene complexes with aldehydes or ketones

…, CJ Rousset, K Aoyagi, M Kotora, T Takahashi…

文献索引：Suzuki, Noriyuki; Rousset, Christophe J.; Aoyagi, Koichiro; Kotora, Martin; Takahashi, Tamotsu; et al. Journal of Organometallic Chemistry, 1994 , vol. 473, # 1-2 p. 117 - 128

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摘要

Abstract Reactions of zirconocene-alkene complexes Cp 2 Zr (CH 2 CHR)(PR′ 3)(R H, Me, Et, SiR ″3 or Ar) with aldehydes or ketones were investigated. Zirconocene-ethylene,- propylene or 1-butene complexes reacted with aldehydes or ketones at terminal carbons of alkenes to give the corresponding alcohols after hydrolysis with a high regioselectivity. A similar type of reaction product was also obtained by a reaction of zirconacyclopentanes ...