Inorganic Chemistry

Reactions of 3-hexyne with cobalt and iron carbonyls. Crystal structure and fluxionality of FeCo2 (CO) 9C2Et2

S Aime, L Milone, D Osella

文献索引：Aime, Silvio; Milone, Luciano; Osella, Domenico; Tiripicchio, Antonio; Manotti Lanfredi, Anna Maria Inorganic Chemistry, 1982 , vol. 21, p. 501 - 505

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被引用次数: 34

摘要

Oxygen incorporation a to the triple bond occurs by reacting a mixture of CO~(CO)~ and Fe (CO), or HFeCo3 (C0) 12 with 3-hexyne: CO~(C~)~ E~ C~ CHOHCH~ and CO~(C~)~ E~ C~ COCH~ are obtained. Other products of the reactions are the two novel mixed-metal derivatives Fe@(CO) 9C2Et2 and F & o (C~)~ E~ C~ CHCH~; the latter is obtained also by dehydroxylation of CO~(C~)~ E~ C~ CHOHCH~ with Fe (CO) 5. The structure of F~ CO~( ...