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A facile preparation of indium enolates and their Reformatsky-and Darzens-type reactions

…, K Kinoshita, H Yamamura, M Kawai, S Araki

文献索引:Hirashita, Tsunehisa; Kinoshita, Kenji; Yamamura, Hatsuo; Kawai, Masao; Araki, Shuki Journal of the Chemical Society, Perkin Transactions 1, 2000 , # 5 p. 825 - 828

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被引用次数: 34

摘要

Indium enolates were readily prepared by transmetalation of lithium enolates with indium trichloride, and were subsequently reacted with aldehydes to give β-hydroxy esters in high yields. Indium α-bromo enolates were also prepared and reacted with carbonyl compounds to give Darzens-type α, β-epoxy carbonyl products.