Synthesis and structural analysis of Bis (2-hydroxyphenyl) phenylamine, PhN (o-C6H4OH) 2: Comparison with Tris (2-hydroxyphenyl) amine N (o-C6H4OH) 3

BV Kelly, JM Tanski, MB Anzovino, G Parkin

文献索引：Kelly, Bryte V.; Tanski, Joseph M.; Anzovino, Mary Beth; Parkin, Gerard Journal of Chemical Crystallography, 2005 , vol. 35, # 12 p. 969 - 981

全文：HTML全文

被引用次数: 6

摘要

Abstract The molecular structures of N (oC 6 H 4 OH) 3, PhN (oC 6 H 4 OH) 2, and p-TolN (oC 6 H 4 OMe) 2 have been determined by X-ray diffraction, thereby indicating several structural differences. For example, whereas the nitrogen in N (oC 6 H 4 OH) 3 is pyramidal with Σ C–N–C= 348.3∘, the nitrogen atoms in PhN (oC 6 H 4 OH) 2 and p-TolN (oC 6 H 4 OMe) 2 are trigonal planar with Σ C–N–C= 359.9∘ and Σ C–N–C= 360.0∘, respectively. ...