Journal of the American Chemical Society

Reagents for organic synthesis. Tin-assisted sulfuration: a highly potent new method for the conversion of carbonyl units into their corresponding thiocarbonyl analogs

K Steliou, M Mrani

文献索引：Steliou,K.; Mrani,M. Journal of the American Chemical Society, 1982 , vol. 104, p. 3104

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被引用次数: 78

摘要

Abstract: Treating bis (tricyclohexy1tin) sulfide with boron trichloride in the presence of a carbonyl-containing compound converts the carbonyl unit into its corresponding thiocarbonyl analogue in high yield. Using this technique, several examples of thioaldehydes, thioketones, thiolactones, and thiolactams were prepared. This potent new sulfurating method is efficient even with highly hindered ketones such as di-tert-butyl ...