前往化源商城

The phase behaviour of 1-alkyl-3-methylimidazolium tetrafluoroborates; ionic liquids and ionic liquid crystals

JD Holbrey, KR Seddon

文献索引:Holbrey, John D.; Seddon, Kenneth R. Journal of the Chemical Society - Dalton Transactions, 1999 , # 13 p. 2133 - 2139

全文:HTML全文

被引用次数: 989

摘要

Air-and water-stable 1-alkyl-3-methylimidazolium tetrafluoroborate salts with the general formula [Cn-mim][BF4](n= 0–18) have been prepared by metathesis from the corresponding chloride or bromide salts. The salts have been characterised by 1H NMR and IR spectroscopy, microanalysis, polarising optical microscopy and differential scanning calorimetry. Those with short alkyl chains (n= 2–10) are isotropic ionic liquids at room ...