Organometallics

Organometallic complexes with electronic bridges. 2. Phenylene-bridged organometallic complexes of iron and manganese

AD Hunter, AB Szigety

文献索引：Hunter, Allen D.; Szigety, Andrew B. Organometallics, 1989 ,  vol. 8, p. 2670 - 2679            

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被引用次数: 45

摘要

The synthesis of the complexes 1, 3-C6H4 (MLn) 2, 14-C6H4 (ML,),, and 1, 3, 5-C6H3 (ML,) 3 (where ML,=(q5-C5Hs) Fe (CO),,(q6-C5H4Me) Fe (C0),, or Mn (CO) 5) is described. These species are best prepared in two steps by metathesis of the organometallic anion, NaML,, with the appropriate aroyl chloride to give acyl intermediates. These complexes were isolated and then thermally decarbonylated (in refluxing butyl ether and THF for the Fe ...