Common phthalate pollutants, such as dimethyl phthalate and diethyl phthalate found in aqueous environmental matrices react with ammonium hydroxide at ordinary temperatures exhibiting an overall reaction order in the range 1.3–1.4. While the reaction is of first order with respect to the phthalate, the order of reaction is fractional in ammonium hydroxide. The rate constants for the reactions of these two phthalates in alkaline waters at ambient ...