Synthesis of Water-Tolerant Indium Homoenolate in Aqueous Media and Its Application in the Synthesis of 1, 4-Dicarbonyl Compounds via Palladium-Catalyzed …

…, CHA Wong, YC Lai, YS Yang, TP Loh

文献索引：Shen, Zhi-Liang; Goh, Kelvin Kau Kiat; Cheong, Hao-Lun; Wong, Colin Hong An; Lai, Yin-Chang; Yang, Yong-Sheng; Loh, Teck-Peng Journal of the American Chemical Society, 2010 , vol. 132, # 45 p. 15852 - 15855

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被引用次数: 38

摘要

The first water-tolerant, ketone-type indium homoenolate was synthesized via the oxidative addition of In/InCl3 to enones. The reaction proceeds exclusively in aqueous media. Both indium and indium (III) chloride are necessary for the smooth conversion of the reaction. ...