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The Ionic Hydrogen/Deuterium Bonds between Diammoniumalkane Dications and Halide Anions

M Demireva, J Oomens, G Berden…

文献索引：Demireva, Maria; Oomens, Jos; Berden, Giel; Williams, Evan R. ChemPlusChem, 2013 , vol. 78, # 9 p. 995 - 1004

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摘要

Abstract Halide-anion binding to 1, 12-dodecanediammonium, tetramethyl-1, 12- dodecanediammmonium, and tetramethyl-1, 7-heptanediammonium has been investigated with infrared multiple-photon dissociation (IRMPD) spectroscopy in the 1000–2250 cm− 1 spectral region and with theory. Both charged ammonium groups in these diammonium compounds interact with the halide anion resulting in an ionic hydrogen bond (IHB) ...