Reactions of 1-hydrosilatrane with 2-hydroxyethylamines

MG Voronkov, GA Kuznetsova, VP Baryshok

文献索引：Voronkov; Kuznetsova; Baryshok Russian Journal of General Chemistry, 2002 , vol. 72, # 7 p. 1148 - 1149

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被引用次数: 1

摘要

Among silatranes, 1-hydrosilatrane (I, SaH) is of considerable theoretical and practical interest, which is due to high and specific reactivity of the Si3H bond [137]. This compound readily reacts with alcohols and phenols [1], alkanediols [2, 3], and carboxylic acids [4]. Dehydrocondensation of I with glucose and mannose yields silatranyl derivatives of monosaccharides [5]. Silatrane I was suggested as an effective reductant [6313].