On the reactivity of organometallic compounds towards functional substrates: IV. The reaction of aliphatic 1-alkynes with triisobutyl-aluminum: Dependence on the …
L Lardicci, AM Caporusso, G Giacomelli
文献索引：Lardicci,L. et al. Journal of Organometallic Chemistry, 1974 , vol. 70, p. 333 - 338
Abstract The reaction between triisobutylaluminum and aliphatic 1-alkynes having alkyl groups of different structure on the 3-carbon atom has been investigated. At room temperature and in the absence of solvents, products which correspond to metallation, reduction and carbalumination processes, are isolated after hydrolysis. The extent of such reactions, and in particular the regiospecificity of the carbalumination is dependent on the ...
