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Journal of Organometallic Chemistry

Decarboxylative allylation of arylglyoxylic acids with allyl alcohol

MF Grünberg, LJ Gooßen

文献索引:Gruenberg, Matthias F.; Goossen, Lukas J. Journal of Organometallic Chemistry, 2013 , vol. 744, p. 140 - 143

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被引用次数: 0

摘要

Abstract A decarboxylative allylation of arylglyoxylic acids with allyl alcohol has been developed. In the presence of catalytic amounts of Pd (dba) 2 and PPh 3, the substrates are in an esterification equilibrium with the allyl arylglyoxylates, which are continuously decarboxylated to give α, β-unsaturated ketones along with CO 2 and water as the only byproducts.