Single-operation synthesis of vinylsilanes from alkenes and hydrosilanes with the aid of Ru3 (CO) 12

Y Seki, K Takeshita, K Kawamoto, S Murai…

文献索引：Seki, Yoshio; Takeshita, Kenji; Kawamoto, Kazuaki; Murai, Shinji; Sonoda, Noboru Journal of Organic Chemistry, 1986 , vol. 51, # 20 p. 3890 - 3895

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被引用次数: 72

摘要

Alkenes (RCH= CHz, where R= CsH5, p-CH3CSH4, p-CHBOC6H4, p-C1CsH4, 2- naphthyl,(CH3) 3C, Me3SiO-(CH3), C, n-C4Hs0, and Et3Si) with HSiEt, with R u~(CO)~~ as a catalyst gave corresponding vinylsilanes (1, 6-13) without formation of simple addition products. Hydrosilanes such as HSiMe,, HSiEhMe, HSiPhMe,, and HSi (OEt), also yielded vinylsilanes. Alkenes having a hydrogen atom at the allylic position (1-hexene, ...