Dioxygen transfer from 4a-hydroperoxyflavin anion. 2. Oxygen transfer to the 10 position of 9-hydroxyphenanthrene anions and to 3, 5-di-tert-butylcatechol anion
S Muto, TC Bruice
文献索引：Muto, Shigeaki; Bruice, Thomas C. Journal of the American Chemical Society, 1980 , vol. 102, # 13 p. 4472 - 4480
Abstract: The reaction of the peroxy anion of Ns-ethyl-4a-hydroperoxy-3-methyllumiflavin (4a- FlEtOl-) with the anions of 3, 5-di-tert-butylcatechol (VIII), IO-ethoxy-9-phenanthrol (Ia), and IO-methyl-9-phenanthrol (Ib) has been investigated. All products may be accountable through the transfer of 0 2 from the 4a-FIEtOl-reactant to the phenolate anions with the production of reduced flavin anion (FIEt-) and a hydroperoxycyclohexadienone. From VIII-( ...
