K3B6O10Cl: a new structure analogous to perovskite with a large second harmonic generation response and deep UV absorption edge

H Wu, S Pan, KR Poeppelmeier, H Li…

文献索引：Wu, Kun-Liang; Mercado, Eduardo V.; Pettus, Thomas R. R. Journal of the American Chemical Society, 2011 , vol. 133, # 16 p. 6114 - 6117

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被引用次数: 228

摘要

Introduction of the Cl–anion in the borate systems generates a new perovskite-like phase, K3B6O10Cl, which exhibits a large second harmonic response, about four times that of KH2PO4 (KDP), and is transparent from the deep UV (180 nm) to middle-IR region. K3B6O10Cl crystallizes in the noncentrosymmetric and rhombohedral space group R 3 m. The structure consists of the A-site hexaborate [B6O10] groups and the BX3 Cl-centered ...