The Journal of Organic Chemistry

Preparation and Reactions of Siloxanylpropanals

W Dennis, J Ryan

文献索引：Dennis,W.E.; Ryan,J.W. Journal of Organic Chemistry, 1970 , vol. 35, p. 4180 - 4183

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被引用次数: 9

摘要

Silanes of the formula R1R2R3SiH add to acetals of acrolein with platinum catalysts to form R1R2RaSiCH2-CHzCH (0R) z. lv2 However, no aldehydes have been prepared from these acetals and characterized except for 3-triethyl~ ilylpropanal~ and 3- diethylmethylsilylpropanal. We wished to prepare compounds having siloxane structures substituted with propanal groups and to study the chemistry of the aldehyde group in such ...