Journal of the American Chemical Society

Hydrogenolysis of succinates and glutarates

B Wojcik, H Adkins

文献索引：Wojcik; Adkins Journal of the American Chemical Society, 1933 , vol. 55, p. 4943

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被引用次数: 8

摘要

The marked labilizing effect of carbinol and carbethoxy groups in the 3 position upon the cleavage of carbon to oxygen linkages has been observed in the hydrogenolysis of trimethylene glycol, ethyl/3-hydroxybut yrate, malonic ester, etc., to the corresponding monohydric alcohols.'The effect of an oxygenated substituent in the 4 or 5 position is less marked than in the 3 position, but may be of considerable importance from a preparational ...